Combustion Analysis Calculator

Determine empirical formula from combustion analysis data. Find mole ratios of C, H, and O from masses of CO2 and H2O produced when burning an organic compound.

🔥 Analysis📐 C from CO2, H from H2O, O by difference🧪 Chemistry
Mass of CO2 produced (g)
Mass of H2O produced (g)
Mass of original compound (g)
Contains N or S? (enter mass N or S if known)
Please enter valid values.

Formula & Reference

VariableSymbolFormulaUnits
Combustion Analysis CalculatorC from CO2, H from H2O, O by differenceempirical formula

Step-by-Step Examples

Example 1
Ascorbic Acid

3.000 g compound gives 4.501 g CO2 and 1.232 g H2O.

  • n(C) = 4.501/44.010 = 0.1023 mol, m(C) = 0.1023x12.011 = 1.228 g
  • n(H) = 1.232/18.015 x 2 = 0.1369 mol, m(H) = 0.1369x1.008 = 0.138 g
  • m(O) = 3.000-1.228-0.138 = 1.634 g, n(O) = 1.634/15.999 = 0.1021
  • Ratios: C:H:O = 0.1023:0.1369:0.1021 divided by 0.1021 = 1:1.34:1
  • Multiply by 3: C3H4O3... simplify to C3H4O3
✓ Empirical formula C3H4O3 (multiply for ascorbic acid C6H8O6)
Example 2
Benzene-type

3.000 g compound gives 10.33 g CO2 and 2.12 g H2O.

  • n(C) = 10.33/44.01 = 0.2347 mol
  • n(H) = 2.12/18.02 x 2 = 0.2353 mol
  • m(C)+m(H) = 2.818+0.237 = 3.055 g > 3.000 g... O<0
  • Compound is pure hydrocarbon (CH ratio ~1:1)
✓ Empirical formula CH (benzene C6H6, toluene C7H8 etc.)
Example 3
Compound with Oxygen

Ethanol: 2.300 g gives 4.399 g CO2, 2.700 g H2O.

  • n(C) = 4.399/44.01 = 0.09994 mol
  • n(H) = 2.700/18.015 x 2 = 0.2998 mol
  • m(O) = 2.300 - 1.200 - 0.302 = 0.798 g, n(O) = 0.798/16 = 0.04988
  • Ratio C:H:O = 0.09994:0.2998:0.04988 / 0.04988 = 2:6:1
✓ Empirical formula C2H6O (ethanol!)

Real-World Applications

🧪
Organic Structure Determination
Standard technique: burn unknown compound, measure CO2 and H2O to find CHO composition.
💊
Drug Purity
Combustion analysis confirms correct molecular formula of pharmaceutical compounds.
🏭
Quality Control
Verify elemental composition of synthetic products matches expected molecular formula.
📚
Biochemistry
Determine empirical formula of natural products, lipids, carbohydrates, and proteins.

Common Mistakes to Avoid

⚠️
All CO2 comes from C only

Moles C = moles CO2. All C in compound converts to CO2 in complete combustion.

⚠️
H2O gives 2 H atoms per molecule

mol H = 2 x mol H2O. Each water contains 2 hydrogen atoms from the organic compound.

⚠️
Oxygen by mass difference

m(O) = m_sample - m(C) - m(H) - m(other). Cannot be measured directly; calculated from mass balance.

Frequently Asked Questions

What is combustion analysis?
An organic compound is completely burned in excess O2. CO2 and H2O produced are weighed. From these masses, the amounts of C and H are determined. Oxygen is found by mass difference.
How do I handle nitrogen in the compound?
Nitrogen appears as N2 (not measured) or NOx. Use the Dumas method (nitrogen analysis) separately. Subtract known N mass from sample mass before finding O by difference.
What is the limit of combustion analysis?
Cannot distinguish between structural isomers (same formula). Cannot determine molecular formula without molar mass. Works only for organic compounds.
How do I convert empirical to molecular formula?
Need molar mass from mass spectrometry. Divide molar mass by empirical formula mass to find n. Molecular formula = n x empirical formula.
Why must combustion be complete?
Incomplete combustion produces CO (not CO2), giving less CO2 and incorrect C calculation. Excess O2 and high T ensure complete combustion.

Related Chemistry Calculators

Formula Explorer connections

Interpretation: This relationship converts chemical amount, mass, composition or balanced-equation ratios into a reaction quantity. Assumption: Use a balanced reaction, consistent units and the correct molar mass. Purity, side reactions and limiting reagents can change experimental results.

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