Combustion Analysis Calculator

Determine empirical formula from combustion analysis data. Find mole ratios of C, H, and O from masses of CO2 and H2O produced when burning an organic compound.

🔥 Analysis📐 C from CO2, H from H2O, O by difference🧪 Chemistry
Mass of CO2 produced (g)
Mass of H2O produced (g)
Mass of original compound (g)
Contains N or S? (enter mass N or S if known)
Please enter valid values.

Formula & Reference

VariableSymbolFormulaUnits
Combustion Analysis Calculator—C from CO2, H from H2O, O by differenceempirical formula

Step-by-Step Examples

Example 1
Ascorbic Acid

3.000 g compound gives 4.501 g CO2 and 1.232 g H2O.

  • n(C) = 4.501/44.010 = 0.1023 mol, m(C) = 0.1023x12.011 = 1.228 g
  • n(H) = 1.232/18.015 x 2 = 0.1369 mol, m(H) = 0.1369x1.008 = 0.138 g
  • m(O) = 3.000-1.228-0.138 = 1.634 g, n(O) = 1.634/15.999 = 0.1021
  • Ratios: C:H:O = 0.1023:0.1369:0.1021 divided by 0.1021 = 1:1.34:1
  • Multiply by 3: C3H4O3... simplify to C3H4O3
✓ Empirical formula C3H4O3 (multiply for ascorbic acid C6H8O6)
Example 2
Benzene-type

3.000 g compound gives 10.33 g CO2 and 2.12 g H2O.

  • n(C) = 10.33/44.01 = 0.2347 mol
  • n(H) = 2.12/18.02 x 2 = 0.2353 mol
  • m(C)+m(H) = 2.818+0.237 = 3.055 g > 3.000 g... O<0
  • Compound is pure hydrocarbon (CH ratio ~1:1)
✓ Empirical formula CH (benzene C6H6, toluene C7H8 etc.)
Example 3
Compound with Oxygen

Ethanol: 2.300 g gives 4.399 g CO2, 2.700 g H2O.

  • n(C) = 4.399/44.01 = 0.09994 mol
  • n(H) = 2.700/18.015 x 2 = 0.2998 mol
  • m(O) = 2.300 - 1.200 - 0.302 = 0.798 g, n(O) = 0.798/16 = 0.04988
  • Ratio C:H:O = 0.09994:0.2998:0.04988 / 0.04988 = 2:6:1
✓ Empirical formula C2H6O (ethanol!)

Real-World Applications

🧪
Organic Structure Determination
Standard technique: burn unknown compound, measure CO2 and H2O to find CHO composition.
💊
Drug Purity
Combustion analysis confirms correct molecular formula of pharmaceutical compounds.
🏭
Quality Control
Verify elemental composition of synthetic products matches expected molecular formula.
📚
Biochemistry
Determine empirical formula of natural products, lipids, carbohydrates, and proteins.

Common Mistakes to Avoid

⚠️
All CO2 comes from C only

Moles C = moles CO2. All C in compound converts to CO2 in complete combustion.

⚠️
H2O gives 2 H atoms per molecule

mol H = 2 x mol H2O. Each water contains 2 hydrogen atoms from the organic compound.

⚠️
Oxygen by mass difference

m(O) = m_sample - m(C) - m(H) - m(other). Cannot be measured directly; calculated from mass balance.

Frequently Asked Questions

What is combustion analysis? ▾
An organic compound is completely burned in excess O2. CO2 and H2O produced are weighed. From these masses, the amounts of C and H are determined. Oxygen is found by mass difference.
How do I handle nitrogen in the compound? ▾
Nitrogen appears as N2 (not measured) or NOx. Use the Dumas method (nitrogen analysis) separately. Subtract known N mass from sample mass before finding O by difference.
What is the limit of combustion analysis? ▾
Cannot distinguish between structural isomers (same formula). Cannot determine molecular formula without molar mass. Works only for organic compounds.
How do I convert empirical to molecular formula? ▾
Need molar mass from mass spectrometry. Divide molar mass by empirical formula mass to find n. Molecular formula = n x empirical formula.
Why must combustion be complete? ▾
Incomplete combustion produces CO (not CO2), giving less CO2 and incorrect C calculation. Excess O2 and high T ensure complete combustion.

Related Chemistry Calculators

Formula Explorer connections

Interpretation: This relationship converts chemical amount, mass, composition or balanced-equation ratios into a reaction quantity. Assumption: Use a balanced reaction, consistent units and the correct molar mass. Purity, side reactions and limiting reagents can change experimental results.

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